Klozur activated sodium fmc chemicals has recently emerged as a robust chemical oxidant for treatment of soil and groundwater contamination. Ecological information ecotoxicity ecotoxicity effects sodium persulfate 7775271 active ingredients duration species value units sodium persulfate 96 h lc50 rainbow trout 163 mgl sodium persulfate 48 h lc50 daphnia magna3 mgl sodium persulfate 96 h lc50 grass shrimp 519 mgl. It is used to raise the ph of soil and water to act as an activator of sodium persulfatein a water. Convert grams sodium persulfate to moles or moles sodium persulfate to grams. With customers in 55 countries across 5 continents, we source and sell most chemicals. Persulfates are strong oxidants that have a wide variety of industrial applications. For over a decade, persulfate has been used to oxidize contaminants in situ. Barker2 1department of civil and environmental engineering, university of waterloo, 200 university ave. In more detail ammonium, potassium, and sodium persulfates are. The proposed treatment uses sodium persulfate and sodium hydroxide to convert insoluble cyanides into soluble form.
Sodium persulfate market global industry analysis 2024. Also the strict regulations for the disposal of waste water from the chemical industry can be a major driver for the sodium. Show this material safety data sheet to the doctor in. First aid measures general advice remove from exposure, lie down. Gradual decomposition at room temperature, heating or rapidly decompose in ethanol, decomposition to release oxygen and produce sodium pyrosulfate. Sodium persulfate is the inorganic compound with the formula na2s2o8. Dissolution of a persulfate salt such as sodium persulfate na 2 s 2 o 8 in water liberates persulfate anion s 2 o 82, which is an oxidizer. Decomposition of insoluble cyanide in contaminated soil by. Sodium persulfate is an inorganic compound and is the sodium salt of persulfate which is also known as peroxydisulfate.
Implementation of strict regulations regarding waste water treatment and growth in usage of sodium persulfate in the process are. Could anyone can explain why aps is preferred for 2. Sodium persulfate is the inorganic compound with the formula na 2 s 2 o 8. Safety data sheet creation date 24nov2010 revision date 18jan2018 revision number 3 1. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Alkaline activated klozur persulfate alkaline activated klozur persulfate, u. Stoichiometric analyses confirmed that hydroperoxide reacts with persulfate in a 1. The reaction started as soon as the salt was added and produced quite a bit of heat, i think it nearly boiled, which is why you need water ready to add to cool and slow the reaction. Sodium persulfate market persistence market research.
The growing textile industry is also expected to create a buzz in the sodium persulfate market. Like ammonium persulfate crystals, they are used as an alternative to the traditional ferric chloride to produce a cleaner copper etchant solution. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Proper shipping name sodium persulfate hazard class 5. Sigmaaldrich used to sell sodium disulfate fused with sodium bisulfate. Decomposition rates of 4% solutions decomposition rates. Uses advised against not for food, drug, pesticide or biocidal product use. C 116 17 86 physical and chemical properties of persulfates. In test 3, a volume of 1 ml of thiosulfate stock solution was added to the dissolved ferrous ion solution and resulted in.
Ammonium persulfate aps and potassium persulfate kps both are commonly used as redox initiator in radical polymerization reaction. Sodium persulfate is a moderately water and acid soluble sodium source for uses compatible with sulfates. It is the sodium salt of peroxydisulfuric acid, h2s2o8, an oxidizing agent. Extreme high moderate low section 1 chemical product and company identification product name sodium persulfate statement of hazardous nature considered a hazardous substance according to osha 29 cfr 1910. Determination of total phosphorus using sodium persulfate. Finoric, etymologically derived from our business line of fine inorganic, organic and industrial chemicals, is the internationally preferred source for chemicals.
Molecular weight of sodium persulfate convert units. Sodium persulfate has the potential to insitu destruct chlorinated and nonchlorinated organic compounds commonly encountered in contaminated soil and groundwater. Sodium persulfate supplier and manufacturers represantative. Pce oxidation by sodium persulfate in the presence of solids. Persulfate decomposition kinetics in the presence of aquifer. All three salts decompose before melting upon heating to 100 c or higher. Sodium persulfate, sodium persulfate supplier, sodium persulfate distributor, cas 7775271, sodium persulfate manufacturer, sodium persulfate wholesale skip to main content covid19 status. Identification product name sodium persulfate cat no. Traditional methods of activation are known to be shortlived, requiring multiple. Persulfate decomposition in phenoxides activated persulfate systems at basic ph. In aqueous solution, persulfates undergo selfdecomposition, which is accelerated by. Consult the flinn scientific website for current prices. This study explored the fundamental mechanisms behind the acceleration and retardation of initial persulfate decomposition by surfactants.
Sodium persulphate 4101 copper etchant sodium persulfate is a good replacement for ammonium persulfate for its compatibility with etch resist pens. Sodium persulfate is not combustible, but assists combustion of combustible materials due to release of oxygen. It also treats a wide range of organic compounds including. When the salts are dissolved in water the persulfate ion is formed, which then goes on to oxidize copper to the cupric ion. Aug 15, 2010 the basecatalyzed hydrolysis of persulfate was supported by kinetic analyses of persulfate decomposition at various base. Second, it should keep away from sunlight, heat sources and moisture. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Sodium pyrosulfate can be easily made by heating sodium bisulfate at temperatures between 200400 c. Submitted by gary cronk, jag consulting group, inc. Parchem is open and ready to supply materials 18002823982 read more.
The salt is prepared by the electrolytic oxidation of sodium hydrogen sulfate. The remaining catalyst continues the formation of the desired pollutant destroying oxidation reactions. The basecatalyzed hydrolysis of persulfate was supported by kinetic analyses of persulfate decomposition at various base. Chapter 28 persulfate decomposition kinetics in the presence of aquifer materials kanwartej s. Alkaline activation hydrogen peroxide activation iron activation persulfox sp contains persulfox catalyst2. While various forms of persulfate are used as chemical oxidants in different industries, it is sodium persulfate that is the predominant form of the compound employed in isco processes. It must be stored in a dry location away from heat and a cool, well ventilated area away from all sources of ignition and out of direct sunlight, protected. The sodium persulfate market is driven by the rising demand for personal care products. The micelledriven retarding effect on persulfate decomposition is also implied by the decrease in dmposo 4 peak intensities after cmc in the presence of sobs, as illustrated in fig. Sodium pyrosulfate is rarely available from suppliers.
Reacts with many combustible materials and reducing agents, often vigorously enough to start fires or cause explosions handling chemicals safely 1980 p. Alkaline activated persulfate forms oxidative radical species, reductants, and nucleophiles furman et al, 2010. It is the sodium salt of peroxydisulfuric acid, h 2 s 2 o 8, an oxidizing agent. The small loss of persulfate in the homogeneous control was consistent with the predicted thermal decomposition of s 2 o 8 2 to so 4 reaction 1. When the salts are dissolved in water the persulfate ion is formed, which then.
It is soluble in water and can be stored at room temperature. What is the half time of ammonium persulfate at temperature. May cause sensitization by inhalation and skin contact. Are you planning to see a doctor about switching your medication. Sodium persulfate sds msds sheet, manufacturers represantative. Moreover, some impurities such as defilement, rust, some metals and reducers can cause the decomposition of ammonium persulfate, therefore, these matters should be paid attention to during storage and use. As expected, the rate of persulfate loss in the absence of solids i. The soils used in this study had high and low total cyanide contents of and 50 mgkg, respectively, and free cyanide contents of 360 and 1. Sep, 2019 sodium persulfate is a good replacement for ammonium persulfate. S patent no 7,576,254 and its foreign counterparts, is a widely used technology capable of remediating most common organic contaminants of concern. Increase in usage of cosmetic products is a major driver of the sodium persulfate market. Decomposes gradually under ordinary conditions decomposition is promoted by moisture and heat merck. Standard thermodynamic properties of chemical substances continued molecular. In particular, the decomposition of persulfate by naturally occurring mineral surfaces has not been studied.
However sodium persulfate is more soluble and less expensive than potassium persulfate and therefore it has been tested as the substitute of potassium persulfate in this project. The standard oxidation reduction potential for the reaction. Key insights of future prospects of sodium persulfate market. In test 3, a volume of 1 ml of thiosulfate stock solution was added to the dissolved ferrous ion solution and resulted in a s 2 o 3 2. An activated alkali metal persulfate effectively repulps neutralalkaline wetstrength broke and decolorizes dyes and optical brightener. It exhibits the property of decomposing in alcohol and can also cause fire. First, it should be stored in dry and closed container. How long have you been taking sodium persulfate powder.
I added about 2ml of water, then 1ml of used sodium persulfate etchant, then a tiny pinch of salt. Methods for cleaning up clean up spill area and treat as special waste. Sodium persulfate will not remove etch resist ink and like ammonium persulfate crystals, are used as an alternative to the traditional ferric chloride to produce a cleaner copper etchant solution. Persulfates have the highest oxidation potential of all peroxygen compounds, even higher than, for example, permanganates. Decomposition of the product as supplied at above 65 degree celsius. Due to these outstanding chemical properties, persulfates is the major initiator type for waterbased polymerization and used in a large variety of applications beyond polymers. Pce oxidation by sodium persulfate in the presence of. Jag consulting group presentation at the battelle 6th international conference on remediation of chlorinated and recalcitrant compounds, may 1922, 2008. It is almost nonhygroscopic and has good shelflife. Sep 02, 2014 persulfate s 2 o 8 2 is being used increasingly for in situ chemical oxidation isco of organic contaminants in groundwater, despite an incomplete understanding of the mechanism through which it is converted into reactive species. By replacing sodium persulfate with persulfox sp, the environmental professional gains all the benefits of traditional activation technologies plus the assurance that after the chemical activator is consumed, the catalyst remains behind. Persulfates technical information leading the persulfate market with the highest. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n kent wa 98032 phone.
Sodium persulfate suppliers manufacturers exporters. Ammonium persulfate potassium persulfate sodium persulfate solubilities of persulfate salts maximum solubility of persulfate salts in water solubility ammonium potassium sodium g100g of h 20 persulfate persulfate persulfate 25. Case study comparison of multiple activation methods for sodium persulfate isco treatment gary cronk, p. With customers in 55 countries across 5 continents, we.
Bp26371, o61141, 06114500 casno 7775271 synonyms sodium peroxydisulfate recommended use laboratory chemicals. The kinetics and mechanism of the decomposition of the persulfate ion in. The persulfate anion has an oxidation potential of 2. However, other authors indicate different temperature decomposition. Sodium, ammonium, potassium persulfates all make good copper etches. Technically this compound is the sodium salt of p eroxydisulfate na 2s 2o. Sodium persulfate 2318921 phosphoric acid 2316332 water 2317912 einecs international lists sara 3023043112 extremely hazardous substances.
They can even have catalysts added which then allow them to be used with tin tinlead resists. Sodium persulfate substance information hazmat tool. In situ chemical oxidation of contaminated groundwater by. The concentrations of sodium persulfate and sodium thiosulfate solutions are 4. Sodium hydroxide is commonly called caustic or caustic soda. Structure, properties, spectra, suppliers and links for.
830 789 611 1269 758 1466 963 688 560 449 444 1445 861 374 349 569 1073 1399 1361 1495 1269 369 1304 897 1510 93 524 581 1441 1408 930 339 1492 897 1283 1223 1122 722 193 311 281 137 216